Why the colour you pick is not always the colour you saw
A photograph of a red object contains hundreds of different reds — lighting, shadow, reflection and JPEG compression all vary it pixel by pixel. Clicking a single point gives you one of them, and it may not be the one that reads as the object's colour.
Sampling an average over a small area is usually closer to what you perceived, which is why a palette extraction often produces more usable values than a single pick. For brand colours, the authoritative value is in the brand's own guidelines rather than in a photograph of the product.